Chapter 12 Practice Problems

Chapter 12 practice problems working through adiabatic expansion, ideal gas state equations, and partial derivative relations for heat capacity — some surprisingly simple!

Prob 12. 1

In adiabatic expansion of an ideal gas,

equation

is a constant.

Show that the following equation holds.

equation

equation

Prob 12. 2

Suppose a gas behaves according to the law given by pV = f(T).

Here f(T) is a function of temperature. From this, show the following equation.

equation

equation

Also show that the following equation holds.

equation

equation

In an adiabatic change, the following equation is satisfied.

equation

Therefore,

equation

show that it is a constant.

It’s the equation where Q is thought of as a function defined by the two variables p and V.

Earlier we

equation

proved this,

so I’ll substitute it into the above equation.

equation

And I’ll substitute in what was previously proved,

equation

equation

Prob 12. 3

Explain why the following can be written as such.

equation

Here A and B are constants.

From these equations,

equation

show that this holds.

equation

equation

equation

equation

equation

equation

equation

When the temperature is a constant, show that the following is satisfied.

equation

Above we had

equation

but T being constant means dT = 0

i.e.

equation

Show that in an adiabatic change the following equation holds.

equation

This one is easy.

equation

The one below too

equation

Therefore show that in an adiabatic change the following equation is satisfied.

equation

First,

equation

Diving into the second.

equation

Let’s cook up the last equation too.

equation

Prob 12. 4

equation

Using this,

explain the slopes of adiabatic and isothermal on the p-V graph in relation to each other.

equation

Prob 12. 5

Two thermally insulated cylinders A and B of equal volume are connected by a valve each having a piston.

Initially A has its piston completely pulled out and contains a monatomic molecular gas inside the cylinder at temperature T,

B has its piston pushed completely in, and the valve is closed.

After the operation described below is carried out, calculate the final temperature of the gas in each case.

In each operation the initial arrangement starts from the same state, and the heat capacity of the cylinder is neglected.

a) Fully open the valve and pull B’s piston all the way out so that the gas slowly enters into B.

A’s piston is fixed so that it doesn’t move.

Since it was said to be completely thermally insulated, δQ = 0

The reason why it was emphasized that it moved slowly is a reversible change

i.e., it will mean that we can express it as δW = -pdV.

equation


Originally written in Korean on my Naver blog (2016-01). Translated to English for gdpark.blog.